Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives - Normandie Université Access content directly
Journal Articles Chemical Communications Year : 2021

Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives

Abstract

An unprecedented enantioselective conjugate addition reaction of sodium bisulfite to various nitrostyrenes occurred upon the influence of a bifunctional amino-thiourea organocatalyst; a strategy that opens a straightforward route to unprotected chiral taurine derivatives thanks to the reduction of the obtained β-nitroethanesulfonic acids into the corresponding amino derivatives.
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Dates and versions

hal-03322399 , version 1 (19-08-2021)

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Emmanuel Deau, Alexandra Le Foll, Clémence Fouache, Emilie Corrot, Laetitia Bailly, et al.. Organocatalytic enantioselective synthesis of β-amino sulfonic acid derivatives. Chemical Communications, 2021, 57, pp.8348 - 8351. ⟨10.1039/D1CC03477D⟩. ⟨hal-03322399⟩
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