Hydrothermal Synthesis and Crystal Structure of Three-dimensional Supramolecular Zinc, Manganese Coordination Polymers - Normandie Université Access content directly
Journal Articles Inorganic and Nano-Metal Chemistry Year : 2019

Hydrothermal Synthesis and Crystal Structure of Three-dimensional Supramolecular Zinc, Manganese Coordination Polymers

Zhi-Tao Wang
  • Function : Author
Qian-Rong Fang
  • Function : Author
Xiu-Mei Li
  • Function : Author
Ya-Ru Pan
  • Function : Author

Abstract

Hydrothermal Synthesis and Crystal Structure of Three-dimensional Supramolecular Zinc, Manganese Coordination Polymers Zhi-Tao Wang • Valentin Valtchev • Qian-Rong Fang • Xiu-Mei Li • Ya-Ru Pan Two new complexes [Zn 2 (pzdc)(L) 2 (H 2 O)] 2n •2nH 2 O (1) and [Mn(µ 2-O)(H 2 O) 2-(HL)] 2n •2nNIPH (2) (H 2 pzdc = pyrazine-2,3-dicarboxylic acid, HL = 3-(2-Pyridyl) pyrazole, H 2 NIPH = 5-nitroisophthalic acid) have been hydrothermally synthesized and structurally characterized by elemental analysis, IR spectrum, UV spectrum, TG, fluorescence spectrum and single-crystal X-ray diffraction. Complex 1 shows two-dimensional (2D) network, which was stabilized by O-H•••O, C-H•••O hydrogen bonding and π-π interactions and extended into 3D supramolecular architecture. Complex 2 is zero-dimensional structure, which was further extended into 3D supramolecular framework through N-H•••O, O-H•••O, C-H•••O hydrogen bonds and π-π interactions.
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Dates and versions

hal-03039949 , version 1 (17-12-2020)

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Zhi-Tao Wang, Valentin Valtchev, Qian-Rong Fang, Xiu-Mei Li, Ya-Ru Pan. Hydrothermal Synthesis and Crystal Structure of Three-dimensional Supramolecular Zinc, Manganese Coordination Polymers. Inorganic and Nano-Metal Chemistry, 2019, 49 (2), pp.44-50. ⟨10.1080/24701556.2019.1586724⟩. ⟨hal-03039949⟩
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