Kinetic Study and Modeling of Peroxypropionic Acid Synthesis from Propionic Acid and Hydrogen Peroxide Using Homogeneous Catalysts - Normandie Université Access content directly
Journal Articles Industrial and engineering chemistry research Year : 2008

Kinetic Study and Modeling of Peroxypropionic Acid Synthesis from Propionic Acid and Hydrogen Peroxide Using Homogeneous Catalysts

Tapio Salmi
  • Function : Author
Dmitry Yu. Murzin
Johan Wärnå
  • Function : Author
Niko Musakka
  • Function : Author

Abstract

This article describes a kinetic study of the perhydrolysis of propionic acid with sulfuric acid at various molar reactant ratios (PA-H2O2 from 0.4 to 2.05), reaction temperatures (from 30 to 60 °C), and catalyst concentrations (from 0 to 1.41 M). The influence of water and acidic catalysts were taken into account to develop a suitable kinetic model. The system is nonideal, mainly due to the presence of the strong electrolyte (i.e., H2SO4), and a parameter was introduced to describe the nonideality. The kinetic and thermodynamic parameters determined by nonlinear regression analysis were statistically well identified. The standard enthalpy change of reaction was estimated to −4.17 kJ·mol-1, and the activation energy of the reaction was estimated to 44.2 kJ·mol-1.
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Dates and versions

hal-02017711 , version 1 (13-02-2019)

Identifiers

  • HAL Id : hal-02017711 , version 1

Cite

Sébastien Leveneur, Tapio Salmi, Dmitry Yu. Murzin, Lionel Estel, Johan Wärnå, et al.. Kinetic Study and Modeling of Peroxypropionic Acid Synthesis from Propionic Acid and Hydrogen Peroxide Using Homogeneous Catalysts. Industrial and engineering chemistry research, 2008, 47 (3), pp.656-664. ⟨hal-02017711⟩
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