Synthesis of Triaminocyclopentadienyl Iron(II) Tricarbonyl Complexes and Application to the Synthesis of Aminophosphines - Normandie Université Accéder directement au contenu
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2023

Synthesis of Triaminocyclopentadienyl Iron(II) Tricarbonyl Complexes and Application to the Synthesis of Aminophosphines

Résumé

Abstract A new family of triaminocyclopentadienyl iron(II) tricarbonyl complexes has been synthesized, fully characterized and applied in hydrogenation transfer. These complexes are the first Earth‐abundant metal complexes able to catalyze reductive alkylation of primary and secondary aliphatic amines with 2‐diarylphosphinobenzaldehyde derivatives at room temperature. These non‐pincer type cyclopentadienyl iron(II) complexes demonstrate not only better efficiency than known cyclopentadienone iron carbonyl complexes but also high functionality tolerance. The resulting aminophosphines provide a straightforward and rapid access to potential P−N ligands.

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Chimie Chimie
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Dates et versions

hal-04222496 , version 1 (29-09-2023)

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Quentin Gaignard Gaillard, Léo Bettoni, Déborah Paris, Clémence Lequertier, Jean‐françois Lohier, et al.. Synthesis of Triaminocyclopentadienyl Iron(II) Tricarbonyl Complexes and Application to the Synthesis of Aminophosphines. Advanced Synthesis and Catalysis, 2023, ⟨10.1002/adsc.202300755⟩. ⟨hal-04222496⟩
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