Dearomatization of a 3-Hydroxypyridine through an unexpected Oxidative Deformylation Process: an Entry to Aza-cyclohexadienones
Résumé
Phenols are well-known precursors of cyclohexadienones, which have found useful widespread applications in organic synthesis. In contrast, their hydroxypyridine counterparts have not been explored yet. An unprecedented oxidative dearomatization of 3-hydroxypyridine involving an unexpected deformylation step, is reported. The chemical reactivity of the subsequent unreported aza-cylohexadiene-type compound, was also explored.
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