Study of the Structure, Acidic, and Catalytic Properties of Binary Mixed-Oxide MoO 3 −ZrO 2 Systems - Normandie Université Access content directly
Journal Articles Chemistry of Materials Year : 2006

Study of the Structure, Acidic, and Catalytic Properties of Binary Mixed-Oxide MoO 3 −ZrO 2 Systems

Abstract

Binary mixed-oxide materials based on MoO3−ZrO2 (1−68 wt/wt MoO3 nominal content) were prepared by a sol−gel method. The samples were characterized after calcination at 873 K by X-ray diffraction, Raman, UV−vis, and infrared spectroscopy. An increase in the molybdenum content produces an increase in the surface area up to ca. 140 m2 g-1 for a nominal MoO3 content of ca. 20 wt/wt. Simultaneously, the progressive generation of Brönsted acid sites attributed to the presence of surface polymolybdate species takes place. The Zr(MoO4)2 crystalline phase coexists with polymolybdate species for catalysts with a nominal MoO3 content higher than 20 wt/wt. These samples show a lower surface area, but the number of Brönsted acid sites per unit of surface area remains almost constant up to ca. 30 wt/wt MoO3 content. A relationship between the structure of molybdenum surface species, the surface acidity determined by the adsorption of 2,6-dimethylpyridine, and the catalytic behavior of materials in the 2-propanol dehydration are reported.

Domains

Catalysis

Dates and versions

hal-02399963 , version 1 (09-12-2019)

Identifiers

Cite

Bárbara Samaranch, Pilar Ramírez de La Piscina, Guillaume Clet, Marwan Houalla, Narcís Homs. Study of the Structure, Acidic, and Catalytic Properties of Binary Mixed-Oxide MoO 3 −ZrO 2 Systems. Chemistry of Materials, 2006, 18 (6), pp.1581-1586. ⟨10.1021/cm052433c⟩. ⟨hal-02399963⟩
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