Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols - Normandie Université
Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2018

Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols

Résumé

Lithium imide enolates featuring Evans’ chiral oxazolidinone auxiliary were involved in diastereoselective α‐trifluoromethylthiolation with electrophilic SCF3 donors. Diastereopure products were isolated and converted to enantiopure α‐SCF3 alcohols without racemisation.

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Chimie

Madeleine ROUX-MERLIN  : Connectez-vous pour contacter le contributeur

https://normandie-univ.hal.science/hal-02024484

Soumis le : mardi 19 février 2019-11:09:08

Dernière modification le : vendredi 19 avril 2024-12:28:17

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hal-02024484 , version 1 (19-02-2019)

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Citer

Hélène Chachignon, Evgeniy V. Kondrashov, Dominique Cahard. Diastereoselective Electrophilic Trifluoromethylthiolation of Chiral Oxazolidinones: Access to Enantiopure α‐SCF3 Alcohols. Advanced Synthesis and Catalysis, 2018, 360 (5), pp.965-971. ⟨10.1002/adsc.201701474⟩. ⟨hal-02024484⟩

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