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Article Dans Une Revue Comptes Rendus. Chimie Année : 2018

Ring-closing metathesis of fluoroalkenes toward the synthesis of fluorinated heterocycles containing an oxaza bond

Résumé

This study reports the ring-closing metathesis reaction of bisolefins, including a reluctant fluoroalkenes, linked with oxaza moiety. The resulting heterocycles were produced in high yields under high diluting conditions disfavoring the homodimerization side reaction of nonfluorinated double bond. The use of a mixture of solvents proved to be a good strategy to obtain the fluorinated heterocycles in fair to excellent yields.

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Chimie organique
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hal-01822900 , version 1 (27-05-2024)

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David Guerin, Isabelle Dez, Annie-Claude Gaumont, Xavier Pannecoucke, Samuel Couve-Bonnaire. Ring-closing metathesis of fluoroalkenes toward the synthesis of fluorinated heterocycles containing an oxaza bond. Comptes Rendus. Chimie, 2018, 21 (8), pp.740-748. ⟨10.1016/j.crci.2017.09.005⟩. ⟨hal-01822900⟩
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