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Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2015

Palladium(II)-Catalysed Oxidation of Alkenes

Résumé

This review provides a summary of recent developments in the palladium(II)-catalysed oxidation of alkenes, focusing largely on reactions which lead to the formation of new carbon–oxygen or carbon–nitrogen bonds. Three classes of reaction are covered: i) oxidations proceeding via allylic C–H bond cleavage and formation of a π-allyl complex; ii) Wacker-type oxidations proceeding via nucleopalladation followed by β-hydride elimination; and iii) 1,2-difunctionalisation of alkenes proceeding via nucleopalladation followed by functionalisation of the resulting σ-alkylpalladium(II) intermediate. The mechanisms are discussed alongside the scope and limitations of each reaction.

Domaines

Chimie

Dates et versions

hal-04344272 , version 1 (14-12-2023)

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Paternité

Identifiants

Citer

Sam Mann, L. Benhamou, Tom Sheppard. Palladium(II)-Catalysed Oxidation of Alkenes. Synthesis: Journal of Synthetic Organic Chemistry, 2015, 47 (20), pp.3079-3117. ⟨10.1055/s-0035-1560465⟩. ⟨hal-04344272⟩

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