Optical properties and structure of Ag-doped InP quantum dots prepared by a phosphine synthetic route - Normandie Université Access content directly
Journal Articles Dalton Transactions Year : 2018

Optical properties and structure of Ag-doped InP quantum dots prepared by a phosphine synthetic route

Abstract

We report a novel technique for doping InP quantum dots (QDs) with silver that makes use of a AgCl TOP complex as a source of silver and PH3 as a phosphorus precursor. Formation of two types of nanoparticles in the reaction mixture is observed Ag-doped InP QDs form at lower silver concentrations and novel Ag/InP core-shell nanostructures form at high Ag-precursor concentrations. Ag-doped QDs possess two luminescent bands an excitonic band at approx. 670 nm and an IR-band, indicative of dopant luminescence, at approx. 900 nm. Post-synthetic covering of the quantum dots with ZnS leads to a significant increase in both types of luminescence. The core-shell Ag/InP nanoparticles did not emit any luminescence in the visible and near-IR spectral regions.

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Materials
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Dates and versions

hal-02174398 , version 1 (05-07-2019)

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Alexander Vinokurov, Galina Chernysheva, Natalia Mordvinova, Sergey Dorofeev. Optical properties and structure of Ag-doped InP quantum dots prepared by a phosphine synthetic route. Dalton Transactions, 2018, 47 (35), pp.12414-12419. ⟨10.1039/c8dt02434k⟩. ⟨hal-02174398⟩
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