Article Dans Une Revue Industrial and engineering chemistry research Année : 2015

Carbonation of Vegetable Oils: Influence of Mass Transfer on Reaction Kinetics

Résumé

The carbonation of vegetable oils was studied by using tetra-n-butylammonium bromide (TBAB) as catalyst. Thermal stability of TBAB was studied by differential scanning calorimetry and thermogravimetric analysis, and it was demonstrated that the maximum reaction temperature should not exceed 130 °C. Reaction conditions were optimum at 130 °C, 50 bar, with 3.5% mol of catalyst. The gas–liquid mass-transfer coefficient and solubility of CO2 were determined by taking into account the nonideality of the gas phase using Peng–Robinson state equations. At 130 °C, the CO2 solubility was found to be independent from epoxide conversion and equal to 0.57 mol·L–1, and the gas–liquid mass-transfer coefficient (kLa) decreases with the epoxide conversion, i.e., at 0% of conversion kLa = 0.0249 s–1 and at 94% of conversion kLa = 0.0021 s–1.

Domaines

Fichier principal
Vignette du fichier
HAL.pdf (1.28 Mo) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Licence

Dates et versions

hal-02138621 , version 1 (17-01-2022)

Licence

Identifiants

Citer

Jun Liu Zheng, Fabrice Burel, Tapio Salmi, Bechara Taouk, Sébastien Leveneur. Carbonation of Vegetable Oils: Influence of Mass Transfer on Reaction Kinetics. Industrial and engineering chemistry research, 2015, 54 (43), pp.10935-10944. ⟨10.1021/acs.iecr.5b02006⟩. ⟨hal-02138621⟩
195 Consultations
368 Téléchargements

Altmetric

Partager

  • More